Non-woven polypropylene fabric modified with carbon nanotubes and decorated with nanoakaganeite for arsenite removal     

J. Tomaszewska  P. Smektała  I. Zgłobicka  J. Michalski  K. J. Kurzydłowski  P. Krzemiński  C. Escudero-Oñate 《International Journal of Environmental Science and Technology》2018,15(9):1831-1842

Due to its harmful impact on human health, the presence of heavy metals, metalloids and other toxic pollutants in drinking or irrigation water is a major concern. Recent studies have proved that nanosized adsorbents are significantly more effective than their microsized counterparts. Particular attention has been given to nanocomposites with nanoadsorbents embedded in matrixes that could provide stability to the material and contribute to eliminating problems that may appear when using conventional granular systems. This study presents the preparation of a novel hybrid filter from a commercially available polypropylene (PP) non-woven fabric matrix modified with multiwall carbon nanotubes (MWCNT) and iron oxy(hydroxide) nanoparticles, and its use in the removal of As(III). A Box–Behnken statistical experimental design has been chosen to explore relevant variables affecting the filter performance: (1) As(III) concentration, (2) pH and (3) sorbent dose. From an As(III) concentration of 10 mg L^?1, at pH 6.5 and with a sorbent dose of 5 g L^?1, the PP filter modified with MWCNT removes 10% of the initial metalloid concentration, reaching a capacity of 0.27 mg g^?1. After modification with iron oxy(hydroxide), the performance of the material is largely enhanced. The filter, under the same conditions, removes 90% of the initial As(III) concentration, reaching a capacity almost tenfold higher (2.54 mg g^?1). This work demonstrates that the developed hybrid filter is effective toward the removal of As(III) in a wide range of pHs. A cubic regression model to compute the removal of the filter as a function of pH and sorbent dose is provided.  相似文献   

Assessment of soil erosion in a tropical mountain river basin of the southern Western Ghats,India using RUSLE and GIS   总被引：1，自引：0，他引：1  

Jobin Thomas  Sabu Joseph  K.P.Thrivikramji 《地学前缘(英文版)》2018,9(3):893-906

Revised Universal Soil Loss Equation(RUSLE) model coupled with transport limited sediment delivery(TLSD) function was used to predict the longtime average annual soil loss, and to identify the critical erosion-/deposition-prone areas in a tropical mountain river basin, viz., Muthirapuzha River Basin(MRB; area=271.75 km~2), in the southern Western Ghats, India. Mean gross soil erosion in MRB is 14.36 t ha~(-1) yr~(-1), whereas mean net soil erosion(i.e., gross erosion-deposition) is only 3.60 t ha~(-1) yr~(-1)(i.e., roughly 25% of the gross erosion). Majority of the basin area(~86%) experiences only slight erosion(5 t ha~(-1) yr~(-1)), and nearly 3% of the area functions as depositional environment for the eroded sediments(e.g., the terraces of stream reaches, the gentle plains as well as the foot slopes of the plateau scarps and the terrain with concordant summits). Although mean gross soil erosion rates in the natural vegetation belts are relatively higher, compared to agriculture, settlement/built-up areas and tea plantation, the sediment transport efficiency in agricultural areas and tea plantation is significantly high,reflecting the role of human activities on accelerated soil erosion. In MRB, on a mean basis, 0.42 t of soil organic carbon(SOC) content is being eroded per hectare annually, and SOC loss from the 4th order subbasins shows considerable differences, mainly due to the spatial variability in the gross soil erosion rates among the sub-basins. The quantitative results, on soil erosion and deposition, modelled using RUSLE and TLSD, are expected to be beneficial while formulating comprehensive land management strategies for reducing the extent of soil degradation in tropical mountain river basins.  相似文献   

Removal of diazinon pesticide from aqueous solutions using MCM-41 type materials: isotherms,kinetics and thermodynamics     

M. A. Amani  A. M. Latifi  K. Tahvildari  R. Karimian 《International Journal of Environmental Science and Technology》2018,15(6):1301-1312

In this research, ordered mesoporous silica, including MCM-41, was synthesized via sol–gel process and a propyl methacrylate-modified ordered mesoporous silica (MPS-MCM-41) was successfully synthesized via a postsynthesis grafting process. Then both MCM-41 and MPS-MCM-41 were characterized using FTIR, XRD, SEM and BET techniques. The synthesized materials were utilized as adsorbent for removal of diazinon pesticide from aqueous solutions. The effects of pH, contact time, adsorbent dose, initial concentration and temperature have been evaluated using removal efficiencies. Also, the kinetic, thermodynamic and isotherm models of diazinon adsorption were studied for the both MCM-41 and MPS-MCM-41. The results showed that the maximum adsorption capacities are 142 and 254 mg g^?1 for the MCM-41 and MPS-MCM-41, respectively, at the initial concentration of 50 mg L^?1, temperature of 298 K and adsorbent dose of 0.1 g L^?1. The highest percentages of diazinon removal are 56.4 and 87.2 (at adsorbent dose of 2 g L^?1 and the temperature of 318 K) for the MCM-41 and MPS-MCM-41, respectively. The Freundlich and Langmuir models are more compatible for describing equilibrium data of the diazinon adsorption capacity on the MCM-41 and MPS-MCM-41, respectively. Thermodynamic study indicated that the adsorption process of diazinon onto MCM-41 and MPS-MCM-41 is exothermic and has a spontaneous nature. The higher adsorption capacity and higher spontaneous nature of MPS-MCM-41 in comparison with MCM-41 might be due to the presence of the both hydrogen bonding and hydrophobic interaction between surface functional groups of MPS-MCM-41 (hydroxyl and propyl methacrylate) and diazinon functional groups.  相似文献   

Preservation of thermophilic mixed culture for anaerobic palm oil mill effluent treatment by convective drying methods     

D. T. Tan  S. K. Chin  P. E. Poh  Y. H. Lee 《International Journal of Environmental Science and Technology》2018,15(6):1211-1222

The generation of huge amount of liquid waste known as palm oil mill effluent is a major problem in oil palm industry. Meanwhile, anaerobic biodegradation of such organic effluent at thermophilic condition is a promising treatment technology due to its high efficiency. However, storage and transportation of thermophilic mixed culture sludge are challenging due to constant biogas generation and heating requirement. Hence, drying of thermophilic sludge was conducted to obtain dormant thermophiles and thus enables easier handling. In this study, thermophilic sludge was dried using heat pump at 22 and 32 °C as well as hot air oven at 40, 50, 60, and 70 °C. Subsequently, quality of dried sludge was examined based on most probable number enumeration, chemical oxygen demand, and methane yield. Average drying rate was found to increase from 3.21 to 17.84 g H₂O/m² min as drying temperatures increases while average moisture diffusivity values ranges from 5.07 × 10^?9 to 4.34 × 10^?8 m²/s. Oven drying of thermophilic mixed culture resulted in highest chemical oxygen demand removal and lowest log reduction of anaerobes at 53.41% and 2.16, respectively, while heat pump drying resulted in the highest methane yield and lowest log reduction of methanogens at 53.4 ml CH₄/g COD and 2.09, respectively. To conclude, heat pump at 22 °C was most suitable drying technique for thermophilic mixed culture as the original methane-producing capability was largely retained after drying, at a slightly lower yet still comparable chemical oxygen demand removal when palm oil mill effluent was treated with the rehydrated culture.  相似文献   

A micromechanical experimental study of highly/completely decomposed tuff granules     

C. S. Sandeep  M. C. Todisco  V. Nardelli  K. Senetakis  M. R. Coop  S. D. N. Lourenco 《Acta Geotechnica》2018,13(6):1355-1367

In this paper, an experimental micromechanical study is presented investigating the contact mechanics and tribological behaviour of highly/completely decomposed tuff granules. The parent material was taken from two locations—named the top and bottom—from a recent landslide in Hong Kong, and in this study the tested granules were obtained from the parent material after drying and sieving processes. Basic material characterisation was conducted quantifying the particle shape, the surface roughness and the strength of a set of grains. A set of twenty-nine monotonic inter-particle shearing tests were conducted on pairs of granules taken from the top and bottom of the landslide. It was found that the granules had very high friction angles at their contacts, in general greater in comparison with other materials reported in the literature. The slightly greater inter-particle friction for the granules taken from the top of the landslide might be because of their higher roughness in comparison with the ones from the bottom. Additional experiments were conducted to investigate the normal and tangential load–displacement response of the granules subjected to cyclic loading. A good curve fitting for the normal load–displacement response could be obtained by using very low apparent Young’s moduli in the Hertzian model. In general, the decomposed tuff granules showed significant plastic response during the first normal load cycle, and this plastic behaviour continued for the subsequent third and fourth cycles. In the cyclic inter-particle shearing tests, the nonlinearity and hysteresis increased for larger cyclic displacements, but the effect of the number of shearing cycles on the energy loss was generally small. Finally, a limited discussion is presented on the applicability of a theoretical model on the tangential load–displacement behaviour of the granules.  相似文献   

Geothermal energy potential of Tulsishyam thermal springs of Gujarat,India     

Hemant Kumar Singh  Aswathi Thankappan  Poonam Mohite  Satish Kumar Sinha  Dornadula Chandrasekharam  Trupti Chandrasekhar 《Arabian Journal of Geosciences》2018,11(6):137

Tulsishyam thermal springs are located in the Saurashtra region of Gujarat, India with discharge temperatures varying from 39 to 42 °C. The pH of these thermal springs varies from 7.1 to 7.4, indicating neutral character. Though these thermal springs propagate through the near surface layer of Deccan basalt, detailed geochemical analysis of the thermal waters using Piper diagram suggests that the water is interacting with the granitic basement rock. Silica and cation geothermometry estimates have reservoir temperature in the range of 138 to 207 °C categorizing it into a low to moderate enthalpy geothermal system. Furthermore, the area has high heat flow values of 53–90 mW/m² because of shallow Moho depth. The prevailing conditions suggest that the geothermal energy can potentially be exploited through an enhanced geothermal system (EGS). The study also indicates different mineral phases that may precipitate out of water during exploitation of geothermal energy and it should be taken into account while designing an EGS for the area.  相似文献   

Rupture of the Indian slab in the 2011 Mw 6.9 Sikkim Himalaya earthquake and its tectonic implications     

T. C. Sunilkumar  Anil Earnest  K. Silp  Ronia Andrews 《《地质学报》英文版》2018,92(Z1):58-58

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Erratum to: The oceanic cycles of the transition metals and their isotopes     

Derek Vance  Corey Archer  Susan H. Little  Michael Köbberich  Gregory F. de Souza 《中国地球化学学报》2018,37(1):151-151

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Geochemical constraints on the tectonic setting of the Sonakhan Greenstone Belt,Bastar Craton,Central India     

S. D. Deshmukh  K. R. Hari  P. Diwan  M. P. Manu Prasanth 《中国地球化学学报》2018,37(3):489-499

The Neo-Archean Sonakhan Greenstone Belt (SGB) located in the north-eastern fringes of Bastar craton, Central India, is dominated by Basalts, Andesites, Dacites and Rhyolites association. Partial melting modeling on the SGB metabasalts indicates that these rocks were derived by 20% melting of spinel peridotite. Fractional crystallisation modeling with REE reveal that the most evolved samples represent the product of fractional crystallization of least evolved magma with 35% plagioclase, 35% clinopyroxene, 20% olivine, 5% magnetite and 5% ilmenite as fractionating minerals with 40% remaining magma. Depletion of HFSE with reference to the LILE and LREE/HFSE ratios and Nb, Zr anomalies in the multi-element diagram of the mafic rocks of SGB indicate Island arc magmatic setting. The enriched Th/Yb values further substantiate that the mantle arrays were modified by subduction-related fluids or melts. The general conclusions drawn indicate that the metabasalts from the SGB were formed as a result of subduction of an intraoceanic lithosphere in a fore-arc suprasubduction zone environment.  相似文献   

Geochemistry and Petrogenesis of Intracontinental Basaltic Volcanism on the Northwest Arabian Plate,Gaziantep Basin,Southeast Anatolia,Turkey     

Sevcan KüRüM  Abdurrahman B?LüCü  Melek URAL 《《地质学报》英文版》2018,92(2):519-535

Volcanism along the northwest boundary of the Arabian Plate found in the Gaziantep Basin, southeast Turkey, is of Miocene age and is of alkaline and calc-alkaline basic composition. The rare earth element data for both compositional series indicates spinel–peridotite source areas. The rare earth and trace elements of the alkaline lavas originate from a highly primitive and slightly contaminated asthenospheric mantle; those of the calc-alkaline lavas originate from a highly heterogeneous, asthenospheric, and lithospheric mantle source. Partial melting and magmatic differentiation processes played a role in the formation of the petrological features of these volcanics. These rocks form two groups on the basis of their ~(87) Sr/~(86) Sr and ~(143) Nd/~(144) Nd isotopic compositions in addition to their classifications based on their chemical compositions(alkaline and calc-alkaline). These isotopic differences indicate a dissimilar parental magma. Therefore, high Nd isotope samples imply a previously formed and highly primitive mantle whereas low Nd isotope samples may indicate comparable partial melting of an enriched heterogeneous shallow mantle. Other isotopic changes that do not conform to the chemical features of these lavas are partly related to the various tectonic events of the region, such as the Dead Sea Fault System and the Bitlis Suture Zone.  相似文献